Do fluorescence and transient absorption probe the same intramolecular charge transfer state of 4-(dimethylamino)benzonitrile? | Zendy

T. Gustavsson | Zendy; Pedro B. Coto | Zendy; Luis SerranoAndrés | Zendy; Takashige Fujiwara | Zendy; Edward C. Lim | Zendy

Open Access

Do fluorescence and transient absorption probe the same intramolecular charge transfer state of 4-(dimethylamino)benzonitrile?

Author(s) -

T. Gustavsson,

Pedro B. Coto,

Luis SerranoAndrés,

Takashige Fujiwara,

Edward C. Lim

Publication year - 2009

Publication title -

the journal of chemical physics

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.071

H-Index - 357

eISSN - 1089-7690

pISSN - 0021-9606

DOI - 10.1063/1.3173609

Subject(s) - benzonitrile , intramolecular force , photochemistry , fluorescence , ultrafast laser spectroscopy , absorption (acoustics) , charge (physics) , transient (computer programming) , chemistry , materials science , optics , physics , stereochemistry , organic chemistry , laser , quantum mechanics , composite material , operating system , computer science

International audienceWe present here the results of time-resolved absorption and emission experiments for 4-(dimethylamino)benzonitrile in solution, which suggest that the fluorescent intramolecular charge transfer (ICT) state may differ from the twisted ICT (TICT) state observed in transient absorption

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