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Arsenic-dominated chemistry in the acid cleaning of InGaAs and InAlAs surfaces
Author(s) -
Yun Sun,
P. Pianetta,
Po-Ta Chen,
Masaharu Kobayashi,
Yoshio Nishi,
Niti Goel,
Michael L. Garner,
Wilman Tsai
Publication year - 2008
Publication title -
applied physics letters
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.182
H-Index - 442
eISSN - 1077-3118
pISSN - 0003-6951
DOI - 10.1063/1.3025852
Subject(s) - arsenic , x ray photoelectron spectroscopy , oxide , annealing (glass) , chemistry , inorganic chemistry , gallium arsenide , materials science , analytical chemistry (journal) , chemical engineering , optoelectronics , metallurgy , environmental chemistry , organic chemistry , engineering
The surface cleaning of InGaAs and InAlAs is studied using Synchrotron Radiation Photoelectron Spectroscopy. Thermal annealing at 400 C can not completely remove the native oxides from those surfaces. Elemental arsenic build-up is observed on both surfaces after acid treatment using HCl, HF or H{sub 2}SO{sub 4} solutions, which is similar to acid-cleaned GaAs surface. Cleaned InGaAs surface is oxide free but small amount of aluminum oxide remains on cleaned InAlAs surface. The common chemical reactions between III-As semiconductors and acid solutions are identified and are found to be dominated by arsenic chemistry.

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