Controlled surface distribution and luminescence of YVO4:Eu3+ nanophosphor layers
Author(s) -
Alima Naim Khan,
D. Haranath,
Ravi Shanker,
Sukhvir Singh,
S. Chawla,
Viresh Dutta
Publication year - 2008
Publication title -
applied physics letters
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.182
H-Index - 442
eISSN - 1077-3118
pISSN - 0003-6951
DOI - 10.1063/1.2973163
Subject(s) - photoluminescence , nanoclusters , materials science , blueshift , luminescence , quantum dot , annealing (glass) , coalescence (physics) , optoelectronics , transmittance , homogeneity (statistics) , analytical chemistry (journal) , molecular physics , nanotechnology , chemistry , composite material , physics , chromatography , astrobiology , statistics , mathematics
A method of dispersing YVO4:Eu quantum dots (QDs) as uniform two-dimensional (2D) layers with a high degree of homogeneity is presented. Annealing at 773 K resulted in coalescence of QDs to form nanoclusters with size of ∼ 25 nm with an improved photoluminescence and ∼ 80% transmittance at 800 nm. An efficient 5D0-7F2 transition and lifetimes of ∼ 1038 μs for the characteristic Eu3+ emission were observed. The absorption and emission peaks showed a slight blueshift, due to quantum-size effect, as compared to that for the bulk counterpart. Our method of 2D layer deposition is useful to enhance spectral response of the solar cells
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