Sol-gel derived nanostructured cerium oxide film for glucose sensor
Author(s) -
Anees A. Ansari,
Pratima R. Solanki,
Bansi D. Malhotra
Publication year - 2008
Publication title -
applied physics letters
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.182
H-Index - 442
eISSN - 1077-3118
pISSN - 0003-6951
DOI - 10.1063/1.2953686
Subject(s) - cerium oxide , glucose oxidase , cerium , materials science , detection limit , sol gel , analytical chemistry (journal) , physisorption , electrode , chemical engineering , amperometry , oxide , electrochemistry , nuclear chemistry , inorganic chemistry , nanotechnology , chemistry , biosensor , catalysis , metallurgy , chromatography , organic chemistry , engineering
Sol-gel derived nanostructured cerium oxide (CeO2) film deposited on gold (Au) electrode has been utilized for physisorption of glucose oxidase (GOx). X-ray diffraction, atomic force microscopy, UV-visible spectroscopy, and electrochemical techniques have been used to characterize sol-gel derived CeO2∕Au electrode and GOx∕CeO2∕Au bioelectrode. The response characteristics of the glucose bioelectrode (GOx∕CeO2∕Au) indicate linearity, detection limit and shelf-life as 50–400mg∕dL, 12.0μM, and 12weeks, respectively. The value of apparent Michaelis–Menten constant (Km) of GOx∕CeO2∕Au bioelectrode has been found to be 13.55μM.
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