Electronic spectra of jet-cooled calix[4]arene and its van der Waals clusters: Encapsulation of a neutral atom in a molecular bowl | Zendy

Takayuki Ebata | Zendy; Yuki Hodono | Zendy; Takafumi Ito | Zendy; Yoshiya Inokuchi | Zendy

Open Access

Electronic spectra of jet-cooled calix[4]arene and its van der Waals clusters: Encapsulation of a neutral atom in a molecular bowl

Author(s) -

Takayuki Ebata,

Yuki Hodono,

Takafumi Ito,

Yoshiya Inokuchi

Publication year - 2007

Publication title -

the journal of chemical physics

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.071

H-Index - 357

eISSN - 1089-7690

pISSN - 0021-9606

DOI - 10.1063/1.2723068

Subject(s) - van der waals force , chemistry , supersonic speed , spectral line , atom (system on chip) , atomic physics , energetic neutral atom , van der waals strain , van der waals radius , molecular physics , molecule , ion , physics , thermodynamics , organic chemistry , astronomy , computer science , embedded system

The encapsulation of neutral guest has been studied for calix[4]arene (C4A) by forming van der Waals clusters with Ar and Ne in supersonic jets. The electronic transitions of these clusters suggest that the first Ar (Ne) is encapsulated inside the C4A cavity, while the next atoms are bound outside.

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