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Luminescence enhancement of (Ca,Zn)TiO3:Pr3+ phosphor using nanosized silica powder
Author(s) -
D. Haranath,
Alima Naim Khan,
Harish Chander
Publication year - 2006
Publication title -
applied physics letters
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.182
H-Index - 442
eISSN - 1077-3118
pISSN - 0003-6951
DOI - 10.1063/1.2338789
Subject(s) - phosphor , photoluminescence , materials science , luminescence , calcium titanate , praseodymium , zinc , doping , ultraviolet , persistent luminescence , anatase , analytical chemistry (journal) , chemical engineering , optoelectronics , photocatalysis , metallurgy , ceramic , chemistry , thermoluminescence , chromatography , biochemistry , engineering , catalysis
The results pertaining to luminescence enhancement due to high-temperature amalgamation of nanometer-sized silica powder and the oxide mixture of calcium, zinc, titanium, and praseodymium are presented. The (Ca,Zn)TiO3:Pr3+ phosphor showed an intense and narrow band emission at ∼614nm under ambient light/ultraviolet excitation, which is associated with the typical H43→D21 transition of Pr3+. The observed red emission is quite stable and long (∼60min) for a dark-adapted human eye and shows no appreciable degradation in the optical properties for prolonged exposure to surrounding/atmosphere. With the addition of nanosized silica powder, the photoluminescence was augmented nearly 1.6 times as that of unadded sample. The present results are entirely different from those reported previously for Pr3+ doped-(Ca,Zn)TiO3 phosphor and silica-based persistent phosphors.

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