Nonequilibrium self-organization phenomena in active Langmuir monolayers
Author(s) -
Tatsuo Shibata,
Alexander S. Mikhailov
Publication year - 2006
Publication title -
chaos an interdisciplinary journal of nonlinear science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.971
H-Index - 113
eISSN - 1089-7682
pISSN - 1054-1500
DOI - 10.1063/1.2213580
Subject(s) - monolayer , non equilibrium thermodynamics , langmuir , molecule , chemical physics , materials science , soft matter , spiral (railway) , coupling (piping) , amphiphile , condensed matter physics , chemistry , nanotechnology , physics , thermodynamics , organic chemistry , adsorption , composite material , polymer , mathematical analysis , mathematics , colloid , copolymer
Langmuir monomolecular layers, formed by amphiphilic molecules at liquid-air interfaces and containing a fraction of chiral molecules, are theoretically investigated. These monolayers can be brought out of thermal equilibrium by applying a gradient of small molecules across the interface, resulting in the leakage flow. We show that, when splay coupling between the orientation field and the local concentration of chiral molecules in the monolayer is taken into account, this nonequilibrium soft matter system can show complex wave behavior, including the development of target wave patterns, spiral waves, and dense regions filled with inwardly propagating waves
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