Open AccessComment on “Dynamic ion association in aqueous solutions of sulfate” [J. Chem. Phys. 123, 034508 (2005)]
Author(s) -
Richard Buchner,
Wolfram W. Rudolph,
Glenn Hefter
Publication year - 2006
Publication title -
the journal of chemical physics
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.071
H-Index - 357
eISSN - 1089-7690
pISSN - 0021-9606
DOI - 10.1063/1.2205861
Subject(s) - aqueous solution , ion association , ion , chemistry , raman spectroscopy , relaxation (psychology) , thermodynamics , sulfate , association (psychology) , statistical physics , chemical physics , computational chemistry , physics , quantum mechanics , organic chemistry , psychology , social psychology , philosophy , epistemology
The "dynamic exchange" model of ion assocn. proposed by Watanabe and Hamaguchi, [J. Chem. Phys.123, 034508 (2005)] for aq. solns. of MgSO4 is shown to be inconsistent with the extensive information available from Raman, relaxation, and thermodn. studies, all of which can be explained by the Eigen equil. model
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