Tunable multiferroic properties in nanocomposite PbTiO3–CoFe2O4 epitaxial thin films
Author(s) -
Makoto Murakami,
KaoShuo Chang,
Maria A. Aronova,
C.-L. Lin,
Ming Yu,
J. Hattrick Simpers,
Manfred Wuttig,
Ichiro Takeuchi,
Chenyan Gao,
Bo Hu,
S. E. Lofland,
L.A. Knauss,
Leonid A. Bendersky
Publication year - 2005
Publication title -
applied physics letters
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.182
H-Index - 442
eISSN - 1077-3118
pISSN - 0003-6951
DOI - 10.1063/1.2041825
Subject(s) - multiferroics , nanocomposite , materials science , dielectric , ferroelectricity , epitaxy , thin film , magnetism , transmission electron microscopy , nanostructure , condensed matter physics , nanotechnology , optoelectronics , physics , layer (electronics)
We report on the synthesis of PbTiO3–CoFe2O4 multiferroic nanocomposites and continuous tuning of their ferroelectric and magnetic properties as a function of the average composition on thin-film composition spreads. The highest dielectric constant and nonlinear dielectric signal was observed at (PbTiO3)85–(CoFe2O4)15, where robust magnetism was also observed. Transmission electron microscopy revealed a pancake-shaped epitaxial nanostructure of PbTiO3 on the order of 30 nm embedded in the matrix of CoFe2O4 at this composition. Composition dependent ferroics properties observed here indicate that there is considerable interdiffusion of cations into each other.
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