Bulk cohesive energy and surface tension from the size-dependent evaporation study of nanoparticles
Author(s) -
Karuna Kar Nanda
Publication year - 2005
Publication title -
applied physics letters
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.182
H-Index - 442
eISSN - 1077-3118
pISSN - 0003-6951
DOI - 10.1063/1.1994958
Subject(s) - surface tension , nanoparticle , evaporation , surface energy , kelvin equation , materials science , thermodynamics , tension (geology) , specific surface energy , chemistry , physics , composite material , nanotechnology , adsorption , ultimate tensile strength
In this letter, it is shown that the bulk cohesive energy $(E_{B})$ andbulk surface tension (\gamma) can be deduced from the size-dependent evaporation (SDE) study of free nanoparticles. The surface tension of nanoparticles $(\gamma_{n})$ is obtained by analyzing SDE data on the basis of the Kelvin equation, while $(E_{B})$ is obtained by reanalyzing the SDE data. By comparing the size-dependent melting and the SDE of nanoparticles, \gamma is evaluated.
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