Near-band-edge slow luminescence in nominally undoped bulk ZnO
Author(s) -
T. Monteiro,
A.J. Neves,
M.C. Carmo,
M.J. Soares,
M. Peres,
J. Wang,
E. Alves,
E. Rita,
U. Wahl
Publication year - 2005
Publication title -
journal of applied physics
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.699
H-Index - 319
eISSN - 1089-7550
pISSN - 0021-8979
DOI - 10.1063/1.1946200
Subject(s) - luminescence , exciton , acceptor , materials science , photoluminescence , spectroscopy , emission spectrum , spectral line , shallow donor , enhanced data rates for gsm evolution , molecular physics , atomic physics , chemistry , optoelectronics , doping , condensed matter physics , physics , telecommunications , quantum mechanics , astronomy , computer science
We report the observation of slow emission bands overlapped with the near-band-edge steady-state luminescence of nominally undoped ZnO crystals. At low temperatures the time-resolved spectra are dominated by the emission of several high-energy bound exciton lines and the two-electron satellite spectral region. Furthermore, two donor-acceptor pair transitions at 3.22 and 3.238 eV are clearly identified in temperature-dependent time-resolved spectroscopy. These donor-acceptor pairs involve a common shallow donor at 67 meV and deep acceptor levels at 250 and 232 meV.FCT/FEDER - POCTI/CTM/45236/0
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