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Low symmetry phase in (001) BiFeO3 epitaxial constrained thin films
Author(s) -
Guangyong Xu,
Haruhiro Hiraka,
G. Shirane,
Jiefang Li,
Junling Wang,
D. Viehland
Publication year - 2005
Publication title -
applied physics letters
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.182
H-Index - 442
eISSN - 1077-3118
pISSN - 0003-6951
DOI - 10.1063/1.1924891
Subject(s) - epitaxy , thin film , materials science , synchrotron , monoclinic crystal system , condensed matter physics , diffraction , scattering , lattice (music) , phase (matter) , crystallography , x ray crystallography , trigonal crystal system , crystal structure , optics , chemistry , nanotechnology , physics , organic chemistry , layer (electronics) , acoustics
The lattice of (001)-oriented BiFeO$_3$ epitaxial thin film has beenidentified by synchrotron x-ray diffraction. By choosing proper scatteringzones containing the fixed (001) reflection, we have shown that low-symmetryphases similar to a $M_A$ phase exist in the thin film at room temperature.These results demonstrate a change in phase stability from rhombohedral in bulksingle crystals, to a modified monoclinic structure in epitaxial thin films

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