Electron-hopping modes in NiMn2O4+δ materials
Author(s) -
Rainer Schmidt,
Arnab Basu,
A.W. Brinkman,
Z. Klusek,
P.K. Datta
Publication year - 2005
Publication title -
applied physics letters
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.182
H-Index - 442
eISSN - 1077-3118
pISSN - 0003-6951
DOI - 10.1063/1.1866643
Subject(s) - variable range hopping , polaron , thermistor , condensed matter physics , quantum tunnelling , electron , materials science , thermal conduction , pellets , atmospheric temperature range , physics , thermodynamics , composite material , quantum mechanics
The resistance versus temperature (R-T) characteristics of NiMn2O4+delta thermistors have been analyzed. In the literature, electron transport in manganate spinels is commonly described by a small-polaron model for nearest neighbor hopping, but variable range hopping (VRH) has not been considered so far. In this study differentiated R-T data were analyzed, allowing a clear distinction between different modes of hopping. In pressed pellets and thick screen printed films conduction was well described by a VRH model for a parabolic density of states, which was confirmed by scanning tunneling spectroscopy
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