The morphotropic phase boundary and dielectric properties of the xPb(Zr1∕2Ti1∕2)O3-(1−x)Pb(Ni1∕3Nb2∕3)O3 perovskite solid solution | Zendy

Naratip Vittayakorn | Zendy; Gobwute Rujijanagul | Zendy; Xiaoli Tan | Zendy; Meagen A. Marquardt | Zendy; David P. Cann | Zendy

Open Access

The morphotropic phase boundary and dielectric properties of the xPb(Zr1∕2Ti1∕2)O3-(1−x)Pb(Ni1∕3Nb2∕3)O3 perovskite solid solution

Author(s) -

Naratip Vittayakorn,

Gobwute Rujijanagul,

Xiaoli Tan,

Meagen A. Marquardt,

David P. Cann

Publication year - 2004

Publication title -

journal of applied physics

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.699

H-Index - 319

eISSN - 1089-7550

pISSN - 0021-8979

DOI - 10.1063/1.1796511

Subject(s) - phase boundary , materials science , ferroelectricity , permittivity , perovskite (structure) , tetragonal crystal system , dielectric , phase diagram , solid solution , phase transition , phase (matter) , analytical chemistry (journal) , mineralogy , condensed matter physics , crystallography , crystal structure , chemistry , physics , optoelectronics , metallurgy , organic chemistry , chromatography

The solid solution between the normal ferroelectric Pb(Zr1∕2Ti1∕2)O3 (PZT) and relaxor ferroelectric Pb(Ni1∕3Nb2∕3)O3 (PNN) was synthesized by the columbite method. The phase structure and dielectric properties of xPZT-(1−x)PNN where x=0.4–0.9 and the Zr∕Ti composition was fixed close to the morphotropic phase boundary (MPB) were investigated. With these data, the ferroelectric phase diagram between PZT and PNN has been established. The relaxor ferroelectric nature of PNN gradually transformed towards a normal ferroelectric state towards the composition 0.7PZT-0.3PNN, in which the permittivity was characterized by a sharp peak and the disappearance of dispersive behavior. X-ray diffraction analysis demonstrated the coexistence of both the rhombohedral and tetragonal phases at the composition 0.8PZT-0.2PNN, a new morphotropic phase boundary within this system. Examination of the dielectric spectra indicates that PZT-PNN exhibits an extremely high relative permittivity near the MPB composition. The permitti...

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