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The Infra-Red Absorption Spectrum of Mono-Deutero-Ethane under High Resolution
Author(s) -
Leroy Raadel Posey,
E. F. Barker
Publication year - 1949
Publication title -
the journal of chemical physics
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.071
H-Index - 357
eISSN - 1089-7690
pISSN - 0021-9606
DOI - 10.1063/1.1747209
Subject(s) - degenerate energy levels , symmetry (geometry) , chemistry , infrared , raman spectroscopy , resolution (logic) , absorption (acoustics) , line (geometry) , spectrum (functional analysis) , plane (geometry) , absorption spectroscopy , molecular physics , analytical chemistry (journal) , physics , optics , mathematics , geometry , quantum mechanics , organic chemistry , artificial intelligence , computer science
The infra‐red spectrum of C2H5D has been investigated under high resolution. As expected, the bands corresponding to degenerate vibrations of C2H6 are split into two components with oscillations in the symmetry plane and normal to the symmetry plane respectively. Analogues of several of the inactive C2H6 frequencies have also been observed, including a pair at 1122 cm−1 and 1159 cm−1 corresponding to a Raman line of ordinary ethane which has been predicted at about 1170 cm−1 but has not as yet been found

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