Vibrational intensity distributions for continuum photoionization of oxygen

Results from measurements of vibrational intensity distributions for continuum photoionization of O2 are reported. Measurements were made using the 584 and 304 A He lines. The photoionization cross section of O2 shows a substantial dip in magnitude over a 20 A band centered about 590 A; thus the possibility exists that a 584 A photoelectron spectrum of O2 includes an autoionized contribution and the vibrational intensity distributions may not correspond to those of continuum ionization. Oxygen photoionization cross section shows no structure around 304 A and purley continuum ionization is expected.