Spin-Resonance Properties of Scheelites. I. Vanadium in CaWO4 | Zendy

Nasser Mahootian | Zendy; Chihiro Kikuchi | Zendy; W. Viehmann | Zendy

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Spin-Resonance Properties of Scheelites. I. Vanadium in CaWO4

Author(s) -

Nasser Mahootian,

Chihiro Kikuchi,

W. Viehmann

Publication year - 1968

Publication title -

the journal of chemical physics

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.071

H-Index - 357

eISSN - 1089-7690

pISSN - 0021-9606

DOI - 10.1063/1.1668769

Subject(s) - vanadium , electron paramagnetic resonance , niobium , table (database) , crystallography , group (periodic table) , microprobe , electron microprobe , resonance (particle physics) , spectral line , spin (aerodynamics) , materials science , nuclear magnetic resonance , chemistry , condensed matter physics , atomic physics , inorganic chemistry , mineralogy , physics , metallurgy , computer science , thermodynamics , organic chemistry , astronomy , data mining

This paper is intended as the first of a series of investigations directed at obtaining information about charge compensation in CaWO4. Vanadium, which lies immediately above niobium in the periodic table, is introduced as the microprobe. The EPR spectra produced by XX irradiation and observed at 77° and 4.2°K indicate that vanadium can occupy a variety of sites. Arguments are given that two of these, referred to as Group A and Group C, are due to vanadiums in W and Ca site, respectively

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