Interactions of Au cluster anions with oxygen

Experimental and theoretical evidence is presented for the nondissociative chemisorption of O2 on free Au cluster anions (Aun-, n=number of atoms) with n=2, 4, 6 at room temperature, indicating that the stabilization of the activated di-oxygen species is the key for the unusual catalytic activities of Au-based catalysts. In contrast to Aun- with n=2, 4, 6, O2 adsorbs atomically on Au monomer anions. For the Au monomer neutral, calculations based on density functional theory reveal that oxygen should be molecularly bound. On Au dimer and tetramer neutrals, oxygen is molecularly bound with the O-O bond being less activated with respect to their anionic counterparts, suggesting that the excess electron in the anionic state plays a crucial role for the O-O activation. We demonstrate that interplay between experiments on gas phase clusters and theoretical approach can be a promising strategy to unveil mechanisms of elementary steps in nanocatalysis.