Polarity determination of a-plane GaN on r-plane sapphire and its effects on lateral overgrowth and heteroepitaxy

Achieving nitride-based device structures unaffected by polarization-induced electric fields can be realized with nonpolar GaN, although polarity plays a key role in the growth. (112¯0) a-plane GaN films were grown on (11¯02) r-plane sapphire substrates and subsequently laterally overgrown using metalorganic chemical vapor deposition. Convergent beam electron diffraction analysis was used to determine the a-GaN polarity to explicitly define the film/substrate relationship, and subsequently to identify various growth features and surfaces observed throughout our studies of a-plane GaN. In particular, the effects of polarity on (1) lateral overgrowth from mask stripe openings aligned along [1¯100]GaN and (2) pit formation in heteroepitaxial films grown under nonoptimized conditions were investigated. The fundamental differences between the polar surfaces are clearly observed; analysis of the lateral epitaxial overgrowth stripes revealed that (0001) surfaces grew faster than (0001) surfaces by approximately...