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Evidence of phosphorus incorporation into InGaAs/InP epilayers after thermal annealing
Author(s) -
S. Hernández,
Noelia Blanco,
I. Mártil,
G. González-Dı́az,
R. Cuscó,
L. Artús
Publication year - 2003
Publication title -
journal of applied physics
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.699
H-Index - 319
eISSN - 1089-7550
pISSN - 0021-8979
DOI - 10.1063/1.1565175
Subject(s) - raman spectroscopy , raman scattering , annealing (glass) , arsenic , materials science , substrate (aquarium) , analytical chemistry (journal) , phosphorus , gallium arsenide , photoluminescence , optoelectronics , chemistry , metallurgy , optics , environmental chemistry , oceanography , physics , geology
We report on Raman scattering measurements on annealed In0.53Ga0.47As/InP layers that reveal the outdiffusion of phosphorus from, the substrate and its, possible incorporation in substitutional positions in. the In0.53Ga0.47As lattice. Raman signal associated with InP-like modes was detected in the annealed samples. The effect is also observed in samples where the substrate was protected by a SiNx:H capping and were annealed in arsenic atmosphere, thus ruling out the possibility of a surface contamination by atmospheric phosphorus evaporated from the InP substrate.. Protruding regions. of a few microns were observed on the surface, which were identified as misoriented In1-xGaP and InP crystals by means of micro-Raman measurements. (C) 2003 American Institute of Physics

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