Ideal magnetocaloric effect for active magnetic regenerators

The active magnetic regenerator (AMR) uses a magnetic solid as a thermal storage medium and as a working material in a refrigeration cycle. Thermodynamically coupled to a heat transfer fluid, the regenerator produces a cooling effect and generates a temperature gradient across the AMR. The coupling between the heat transfer fluid and the magnetic refrigerant is a key aspect governing the operating characteristics of an AMR. To increase our understanding of AMR thermodynamics, we examine the entropy balance in an idealized active magnetic regenerator. A relation for the entropy generation in an AMR with varying fluid capacity ratios is derived. Subsequently, an expression describing the ideal magnetocaloric effect (MCE) as a function of temperature is developed for the case of zero entropy generation. Finally, the link between ideal MCE and refrigerant symmetry is discussed showing that an ideal reverse Brayton-type magnetic cycle cannot be achieved using materials undergoing a second-order magnetic phase ...