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Depth-profiling plasma-induced densification of porous low-k thin films using positronium annihilation lifetime spectroscopy
Author(s) -
Jianing Sun,
David W. Gidley,
Yifan Hu,
W. E. Frieze,
E. Todd Ryan
Publication year - 2002
Publication title -
applied physics letters
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.182
H-Index - 442
eISSN - 1077-3118
pISSN - 0003-6951
DOI - 10.1063/1.1501767
Subject(s) - positronium , materials science , positron annihilation spectroscopy , porosity , dielectric , plasma , x ray photoelectron spectroscopy , spectroscopy , thin film , annihilation , ashing , analytical chemistry (journal) , porous medium , molecular physics , composite material , positron annihilation , chemistry , nuclear magnetic resonance , optoelectronics , nanotechnology , positron , physics , nuclear physics , quantum mechanics , chromatography , electron
Positronium annihilation lifetime spectroscopy (PALS) has been used to depth profile the densification induced in a porous low-dielectric constant (k) thin film by typical device integration processing, including exposure to plasmas and oxygen ashing. Such “integration damage” has previously been observed as an undesirable increase in k accompanied by shrinkage in the porous film thickness. PALS confirms that the structural damage is confined to a surface layer of collapsed pores with the underlying pores being undamaged. The dense layer thickness determined by PALS increases with plasma exposure time. © 2002 American Institute of Physics

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