A vitrifying structure transition in the Dy/Mo(112) adsorption system
Author(s) -
А.Г. Федорус,
V. Koval,
А.Г. Наумовец,
H. Pfnür
Publication year - 2001
Publication title -
low temperature physics
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.356
H-Index - 43
eISSN - 1090-6517
pISSN - 1063-777X
DOI - 10.1063/1.1414575
Subject(s) - annealing (glass) , metastability , materials science , diffraction , crystallography , electron diffraction , adsorption , condensed matter physics , chemistry , optics , metallurgy , physics , organic chemistry
Annealing-driven irreversible structural transitions are studied by low-energy electron diffraction in submonolayer Dy films adsorbed on the Mo(112) surface. In a wide coverage range θ>0.07, Dy overlayers deposited at low temperatures (T≈100 K) are ordered and keep their structure upon annealing up to 350–600 K. Near θ=0.68, the overlayers are stable to high-temperature annealing (Ta=1000 K) as well, whereas the denser films are metastable and transform to more stable ordered structures. An unusual annealing effect is found for θ<0.58: the initially ordered metastable phases are replaced by phases having no extended order, which are assumed to be two-dimensional glasses.
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