Covalent attachment of acetonitrile on Si(100) through Si–C and Si–N linkages | Zendy

Tao Feng | Zendy; Zhong Hai Wang | Zendy; Ming Qiao | Zendy; Qin Liu | Zendy; Wee Sun Sim | Zendy; Guo Qin Xu | Zendy

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Covalent attachment of acetonitrile on Si(100) through Si–C and Si–N linkages

Author(s) -

Tao Feng,

Zhong Hai Wang,

Ming Qiao,

Qin Liu,

Wee Sun Sim,

Guo Qin Xu

Publication year - 2001

Publication title -

the journal of chemical physics

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.071

H-Index - 357

eISSN - 1089-7690

pISSN - 0021-9606

DOI - 10.1063/1.1410388

Subject(s) - x ray photoelectron spectroscopy , acetonitrile , chemisorption , desorption , covalent bond , dimer , binding energy , chemistry , adsorption , thermal desorption spectroscopy , high resolution electron energy loss spectroscopy , density functional theory , crystallography , materials science , electron energy loss spectroscopy , analytical chemistry (journal) , computational chemistry , nanotechnology , organic chemistry , atomic physics , physics , nuclear magnetic resonance , transmission electron microscopy

An analysis of covalent binding and adsorption states of acetonitrile on Si(100) was performed. For this analysis temperature programmed desorption (TPD), X-ray photoelectron spectroscopy (XPS), high-resolution electron energy loss spectroscopy (HREELS) and density functional theory (DFT) were used. The results showed that acetonitrile chemisorbs on Si(100) in a side-on di-σ binding configuration forming Si-C and Si-N σ bonds.

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