Cycloaddition reaction of furan with Si(100)-2×1 | Zendy

Minghua Qiao | Zendy; Franklin Tao | Zendy; Yang Cao | Zendy; Zhaohui Li | Zendy; WeiLin Dai | Zendy; J. F. Deng | Zendy; Guo Qin Xu | Zendy

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Cycloaddition reaction of furan with Si(100)-2×1

Author(s) -

Minghua Qiao,

Franklin Tao,

Yang Cao,

Zhaohui Li,

WeiLin Dai,

J. F. Deng,

Guo Qin Xu

Publication year - 2001

Publication title -

the journal of chemical physics

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.071

H-Index - 357

eISSN - 1089-7690

pISSN - 0021-9606

DOI - 10.1063/1.1338477

Subject(s) - cycloaddition , furan , x ray photoelectron spectroscopy , chemistry , ultraviolet photoelectron spectroscopy , photochemistry , homo/lumo , molecular orbital , covalent bond , spectroscopy , computational chemistry , molecule , electronic structure , organic chemistry , catalysis , physics , nuclear magnetic resonance , quantum mechanics

The adsorption coefficient of furan on Si(100)-2×1 was investigated using various spectroscopic techniques and semiempirical molecular orbital (MO) calculations. Furan was found to be nondissociatively chemisorbed on the Si(100)-2×1 surface at 125 K. The semiempirical simulation of the valence band spectrum of the cycloadduct agreed well with the experimental results.

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