Novel switching phenomena in ferroelectric Langmuir–Blodgett films
Author(s) -
A. V. Bune,
Stephen Ducharme,
V. M. Fridkin,
L. M. Blinov,
S. P. Palto,
N. Petukhova,
Sergey Yudin
Publication year - 1995
Publication title -
applied physics letters
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.182
H-Index - 442
eISSN - 1077-3118
pISSN - 0003-6951
DOI - 10.1063/1.114423
Subject(s) - ferroelectricity , hysteresis , materials science , monolayer , conductance , langmuir–blodgett film , condensed matter physics , ferroelectric polymers , phase transition , optoelectronics , nanotechnology , dielectric , physics
We have established ferroelectric switching and observed a novel conductance switching phenomenon in ferroelectric polymer films fabricated by the Langmuir–Blodgett technique. The films consist of 10–30 monolayers (ML) of a copolymer of vinylidene fluoride (70%) and trifluoroethylene (30%), exhibiting a first‐order ferroelectric phase transition at 70 °C and nearly rectangular ferroelectric and conductance hysteresis at 24 °C. Ferroelectric switching is accompanied by switching of the conductance by three orders of magnitude. A model describing this switching phenomenon is proposed.
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