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A sensitive detector and pressure gauge for uranium hexafluoride in high-vacuum systems is described. Negative surface ionization of UF(6) occurs on ribbon filaments operated at temperatures too low for electron emission to be significant. The ion current measured on a cylindrical collector surrounding the filament assembly varies regularly with UF(6) pressure below 10(-3) Torr. Different filament materials are considered, including rhenium, thoriated tungsten, and platinum. Rhenium is found to be the most satisfactory material for operation of diode emitters as a pressure gauge. Gauge constants (in A Torr(-1)) are derived from comparing negative surface ionization currents with the response of a capacitance manometer and are shown to be independent of temperature within a reasonable operating range. The effects of exposing the rhenium filament to various gases is considered, and it is shown that brief exposure to acetylene substantially improves the operating characteristics of the gauge.

Simple pressure gauge for uranium hexafluoride