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Pulsed-laser induced desorption and subsequent readsorption in ambient gas
Author(s) -
Gregor Holler,
Uwe Albrecht,
Stephan Herminghaus,
P. Leǐderer
Publication year - 1993
Publication title -
applied physics letters
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.182
H-Index - 442
eISSN - 1077-3118
pISSN - 0003-6951
DOI - 10.1063/1.109187
Subject(s) - desorption , ambient pressure , thermal desorption , helium , diffusion , chemistry , carbon dioxide , analytical chemistry (journal) , chemical physics , outgassing , gaseous diffusion , laser , materials science , thermodynamics , adsorption , environmental chemistry , optics , electrode , physics , organic chemistry
We have investigated the phenomenon of readsorption after pulsed‐laser induced thermal desorption during the presence of ambient gas. The temporal evolution of the readsorption of water has been measured as a function of the ambient gas pressure for helium and carbon‐dioxide atmospheres. CO2pressures above 10 mbar lead to a virtually complete readsorption of the desorbed material. A model based on a nearly one‐dimensional diffusion scheme explains this remarkable result

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