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On the origin of visible photoluminescence in nanometer-size Ge crystallites
Author(s) -
Yoshihiko Kanemitsu,
Hiroshi Uto,
Yasuaki Masumoto,
Yoshihito Maeda
Publication year - 1992
Publication title -
applied physics letters
Language(s) - English
Resource type - Journals
eISSN - 1077-3118
pISSN - 0003-6951
DOI - 10.1063/1.108290
Subject(s) - photoluminescence , nanocrystal , materials science , crystallite , nanostructure , nanometre , germanium , diamond , nanotechnology , optoelectronics , silicon , composite material , metallurgy
We have studied the origin of visible photoluminescence of Ge nanocrystals in SiOZ glassymatrix. Spectroscopic analyses of Ge nanocrystals indicate that the room-temperaturephotoluminescence comes from Ge nanocrystals of diameter of 4 nm or less. High-resolutionelectron microscopic studies imply that the structure of Ge nanocrystals of diameter <4 nmdiffers from the diamond structure. These data suggest that new nanostructure crystalline Gehaving a character of direct optical transition exhibits the visible photoluminescence

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