Metal-assisted reactions. Part 25. Heterogeneous and homogeneous catalytic transfer hydrogenolysis of allyloxytetrazoles to yield alkenes or alkanes | Zendy

Maria L. S. Cristiano | Zendy; R. A. W. Johnstone | Zendy; Peter J. Price | Zendy

Open Access

Metal-assisted reactions. Part 25. Heterogeneous and homogeneous catalytic transfer hydrogenolysis of allyloxytetrazoles to yield alkenes or alkanes

Author(s) -

Maria L. S. Cristiano,

R. A. W. Johnstone,

Peter J. Price

Publication year - 1996

Publication title -

journal of the chemical society. perkin transactions i/journal of the chemical society. perkin transactions. i

Language(s) - English

Resource type - Journals

eISSN - 2050-8255

pISSN - 0300-922X

DOI - 10.1039/p19960001453

Subject(s) - hydrogenolysis , alkene , catalysis , yield (engineering) , chemistry , alkane , homogeneous , palladium , metal , photochemistry , heterogeneous catalysis , bond cleavage , hydrogen , organic chemistry , materials science , thermodynamics , physics , metallurgy

Transfer hydrogenolysis of 5-allyloxy- 1-phenyltetrazoles using either a heterogeneous or a homogeneous palladium catalyst and a hydrogen donor leads to cleavage of the allyloxy C-O bond to yield an alkane or an alkene and 1-phenyltetrazolone, depending on the catalyst used

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