Self-assembly of a columnar polymeric calcium phosphinate derived from camphene | Zendy

William Henderson | Zendy; Meto T. Leach | Zendy; Brian K. Nicholson | Zendy; Michal Sabat | Zendy

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Self-assembly of a columnar polymeric calcium phosphinate derived from camphene

Author(s) -

William Henderson,

Meto T. Leach,

Brian K. Nicholson,

Michal Sabat

Publication year - 1995

Publication title -

journal of the chemical society. dalton transactions

Language(s) - English

Resource type - Journals

eISSN - 2050-5671

pISSN - 0300-9246

DOI - 10.1039/dt9950002109

Subject(s) - phosphinate , camphene , calcium , chemistry , lysophosphatidic acid , salt (chemistry) , merge (version control) , polymer chemistry , organic chemistry , biochemistry , chromatography , fire retardant , essential oil , receptor , computer science , information retrieval

(2,2-Dimethylbicyclo[2.2.1] hept-3-ylmethyl)phosphinic acid (RPO₂H₂), readily prepared from camphene and hypophosphorous acid, formed a polymeric calcium salt [{Ca(RPO₂H) ₂ (RPO₂H₂)(H₂O)}n], with both terminal and triply bridging phosphinate groups, and an overall columnar structure with an inorganic core and a pseudo-close-packed sheath of terpene moieties

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