Mn2(CO)10 and UV light: a promising combination for regioselective alkene hydrosilylation at low temperature | Zendy

Anthony Vivien | Zendy; Laurent Veyre | Zendy; Raphaël Mirgalet | Zendy; Clément Camp | Zendy; Chloé Thieuleux | Zendy

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Mn₂(CO)₁₀ and UV light: a promising combination for regioselective alkene hydrosilylation at low temperature

Author(s) -

Anthony Vivien,

Laurent Veyre,

Raphaël Mirgalet,

Clément Camp,

Chloé Thieuleux

Publication year - 2022

Publication title -

chemical communications

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.837

H-Index - 333

eISSN - 1364-548X

pISSN - 1359-7345

DOI - 10.1039/d2cc00377e

Subject(s) - hydrosilylation , regioselectivity , markovnikov's rule , alkene , manganese , chemistry , selectivity , photochemistry , organic chemistry , catalysis

The low temperature regioselective hydrosilylation of various alkenes with (1,1,1,3,5,5,5-heptamethyltrisiloxane) MD H M is described using Mn 2 (CO) 10 under UV irradiation with Mn loadings as low as 1 mol%, in the absence of additives and with excellent selectivity and yields. The generation of a manganese radical allowed the anti-Markovnikov hydrosilylation products to be selectively obtained in yields up to 99%.

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