Open AccessSynthesis and redox activity of carbene-coordinated group 13 metal radicals
Author(s) -
Bin Li,
Blaise L. Geoghegan,
Hanns Micha Weinert,
Christoph Wölper,
George E. Cutsail,
Stephan Schulz
Publication year - 2022
Publication title -
chemical communications
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.837
H-Index - 333
eISSN - 1364-548X
pISSN - 1359-7345
DOI - 10.1039/d2cc00216g
Subject(s) - carbene , radical , chemistry , main group element , metal , redox , group (periodic table) , quantum chemical , crystallography , medicinal chemistry , transition metal , stereochemistry , inorganic chemistry , molecule , organic chemistry , catalysis
One-electron oxidation of carbene-stabilized aluminum and gallium dihalide radicals (3, 4) yielded the corresponding cations (5, 6), whose electronic structures were evaluated by quantum chemical calculations.