Merging C–C σ-bond activation of cyclobutanones with CO2 fixation via Ni-catalysis | Zendy

Lorenzo Lombardi | Zendy; Alessandro Cerveri | Zendy; Leonardo Ceccon | Zendy; Riccardo Pedrazzani | Zendy; Magda Monari | Zendy; Giulio Bertuzzi | Zendy; Marco Bandini | Zendy

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Merging C–C σ-bond activation of cyclobutanones with CO₂ fixation via Ni-catalysis

Author(s) -

Lorenzo Lombardi,

Alessandro Cerveri,

Leonardo Ceccon,

Riccardo Pedrazzani,

Magda Monari,

Giulio Bertuzzi,

Marco Bandini

Publication year - 2022

Publication title -

chemical communications

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.837

H-Index - 333

eISSN - 1364-548X

pISSN - 1359-7345

DOI - 10.1039/d2cc00149g

Subject(s) - electrophile , catalysis , chemistry , tandem , yield (engineering) , functional group , combinatorial chemistry , electrophilic addition , stereochemistry , medicinal chemistry , organic chemistry , materials science , polymer , metallurgy , composite material

A carboxylative Ni-catalyzed tandem C–C σ-bond activation of cyclobutanones followed by CO 2 -electrophilic trapping is documented as a direct route to synthetically valuable 3-indanone-1-acetic acids.

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