From ferrocene to 1,2,3,4,5-pentafluoroferrocene: halogen effect on the properties of metallocene | Zendy

William Erb | Zendy; Nicolas Richy | Zendy; JeanPierre Hurvois | Zendy; Paul J. Low | Zendy; Florence Mongin | Zendy

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From ferrocene to 1,2,3,4,5-pentafluoroferrocene: halogen effect on the properties of metallocene

Author(s) -

William Erb,

Nicolas Richy,

JeanPierre Hurvois,

Paul J. Low,

Florence Mongin

Publication year - 2021

Publication title -

dalton transactions

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.98

H-Index - 184

eISSN - 1477-9234

pISSN - 1477-9226

DOI - 10.1039/d1dt03430h

Subject(s) - ferrocene , metallocene , halogen , chemistry , fluorine , electrochemistry , polymer chemistry , organic chemistry , electrode , polymerization , alkyl , polymer

The sequentially fluorinated ferrocenes (1-, 1,2-di, 1,2,3-tri, 1,2,3,4-tetra and 1,2,3,4,5-pentafluoroferrocene) have been synthesized from ferrocene. Rather than a 'perfluoro' effect, experimental and computational analysis of the complete series robustly demonstrates a linear additive effect of fluorine on the electrochemical and spectroscopic properties of ferrocene.

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