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Si-containing polycyclic aromatic hydrocarbons: synthesis and opto-electronic properties
Author(s) -
Thomas Delouche,
Ghizlene Taifour,
Marie Cordier≈,
Thierry Roisnel,
Denis Tondelier,
Payal Manzhi,
Bernard Geffroy,
Boris Le Guennic,
Denis Jacquemin,
Muriel Hissler,
PierreAntoine Bouit
Publication year - 2021
Publication title -
chemical communications
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.837
H-Index - 333
eISSN - 1364-548X
pISSN - 1359-7345
DOI - 10.1039/d1cc06309j
Subject(s) - heteroatom , luminescence , electroluminescence , chemistry , electronics , organic electronics , redox , solid state , polycyclic aromatic hydrocarbon , aromaticity , photochemistry , combinatorial chemistry , organic chemistry , materials science , molecule , optoelectronics , transistor , ring (chemistry) , physics , layer (electronics) , voltage , quantum mechanics
We report a straightforward synthesis of Si-containing Polycyclic Aromatic Hydrocarbons (PAHs). The impact of π-extension and exocyclic modifications on both the optical and redox properties is investigated using a joint experimental/theoretical approach. By taking advantage of the solid-state luminescence of these derivatives, electroluminescent devices are prepared. Such preliminary opto-electronic results highlight that these heteroatom-containing PAHs are promising building blocks for organic electronics.

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