Synthesis and characterisation of a very low-coordinate diferrous [2Fe–2S]0 unit | Zendy

Christian Schneider | Zendy; Sophie Jana Groß | Zendy; Serhiy Demeshko | Zendy; Sébastien Bontemps | Zendy; Franc Meyer | Zendy; C. Gunnar Werncke | Zendy

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Synthesis and characterisation of a very low-coordinate diferrous [2Fe–2S]⁰ unit

Author(s) -

Christian Schneider,

Sophie Jana Groß,

Serhiy Demeshko,

Sébastien Bontemps,

Franc Meyer,

C. Gunnar Werncke

Publication year - 2021

Publication title -

chemical communications

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.837

H-Index - 333

eISSN - 1364-548X

pISSN - 1359-7345

DOI - 10.1039/d1cc04196g

Subject(s) - mössbauer spectroscopy , rhombus , chemistry , crystallography , cleavage (geology) , magnetic susceptibility , ligand (biochemistry) , ion , stereochemistry , materials science , organic chemistry , mathematics , geometry , receptor , biochemistry , fracture (geology) , composite material

Here we present the synthesis of a unique diferrous [2Fe-2S] 0 complex with only three-coordinate iron ions via reduction of a four-coordinate diferric [2Fe-2S] 2+ complex with concomitant ligand loss. The obtained compounds were thoroughly examined for their properties ( e.g. by 57 Fe Mössbauer spectroscopy and magnetic susceptibility measurements). Facile cleavage of the [2Fe-2S] rhombus, commonly seen as rather stable, by CS 2 is also shown.

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