Open AccessPd/Ni-Catalyzed Germa-Suzuki coupling via dual Ge–F bond activation
Author(s) -
Hajime Kameo,
Akihiro Mushiake,
Tomohito Isasa,
Hiroyuki Matsuzaka,
Didier Bourissou
Publication year - 2021
Publication title -
chemical communications
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.837
H-Index - 333
eISSN - 1364-548X
pISSN - 1359-7345
DOI - 10.1039/d1cc01392k
Subject(s) - phosphine , dual (grammatical number) , catalysis , chelation , coupling (piping) , chemistry , crystallography , materials science , inorganic chemistry , metallurgy , organic chemistry , philosophy , linguistics
Pd/Ni → Ge-F interactions supported by phosphine-chelation were found to trigger dual activation of Ge-F bonds under mild conditions. This makes fluoro germanes suitable partners for catalytic Ge-C cross-coupling and enables Germa-Suzuki reactions to be achieved for the first time.
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