Access to functionalized luminescent Pt(ii) complexes by photoredox-catalyzed Minisci alkylation of 6-aryl-2,2′-bipyridines | Zendy

Wided Hagui | Zendy; Marie Cordier≈ | Zendy; Julien Boixel | Zendy; JeanFrançois Soulé | Zendy

Open Access

Access to functionalized luminescent Pt(ii) complexes by photoredox-catalyzed Minisci alkylation of 6-aryl-2,2′-bipyridines

Author(s) -

Wided Hagui,

Marie Cordier≈,

Julien Boixel,

JeanFrançois Soulé

Publication year - 2020

Publication title -

chemical communications

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.837

H-Index - 333

eISSN - 1364-548X

pISSN - 1359-7345

DOI - 10.1039/d0cc07307e

Subject(s) - aryl , alkylation , chemistry , catalysis , combinatorial chemistry , luminescence , photoredox catalysis , medicinal chemistry , organic chemistry , photocatalysis , physics , alkyl , optoelectronics

Photoredox-mediated C-H bond alkylation of 6-aryl-2,2'-bipyridines with N-(acyloxy)phthalimides is reported. The reaction exhibits excellent functional group tolerance, including chiral aliphatic groups. The influence of the incorporated C6'-alkyl group on the photophysical properties of the corresponding (N^N^C) cyclometalated Pt(ii) complexes is described, including chiroptical properties.

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