Chirality from scratch: enantioselective adsorption in geometrically controlled lateral nanoconfinement | Zendy

Johannes Seibel | Zendy; Zeno Tessari | Zendy; David B. Amabilino | Zendy; Steven De Feyter | Zendy

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Chirality from scratch: enantioselective adsorption in geometrically controlled lateral nanoconfinement

Author(s) -

Johannes Seibel,

Zeno Tessari,

David B. Amabilino,

Steven De Feyter

Publication year - 2020

Publication title -

chemical communications

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.837

H-Index - 333

eISSN - 1364-548X

pISSN - 1359-7345

DOI - 10.1039/d0cc06845d

Subject(s) - enantioselective synthesis , chirality (physics) , adsorption , materials science , scratch , chemical physics , nanotechnology , symmetry (geometry) , symmetry breaking , chiral symmetry breaking , chemical engineering , catalysis , chemistry , geometry , physics , organic chemistry , composite material , mathematics , quantum mechanics , engineering , nambu–jona lasinio model

Chiral symmetry breaking in molecular adsorption at the solid/liquid interface by lateral geometric nanoconfinement is demonstrated. The chiral nanoconfinement is created at the interface of achiral covalently modified highly-oriented pyrolytic graphite and a racemate by in situ scanning probe lithography. Enantioselective adsorption of chiral molecules is achieved by adjusting the relative orientation between the nanoconfining walls and substrate symmetry direction.

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