Chemiluminescent read-out of para-fluoro-thiol reaction events | Zendy

Fabian R. Bloesser | Zendy; Federica Cavalli | Zendy; Sarah L. Walden | Zendy; Leonie Barner | Zendy; Christopher BarnerKowollik | Zendy

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Chemiluminescent read-out of para-fluoro-thiol reaction events

Author(s) -

Fabian R. Bloesser,

Federica Cavalli,

Sarah L. Walden,

Leonie Barner,

Christopher BarnerKowollik

Publication year - 2020

Publication title -

chemical communications

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.837

H-Index - 333

eISSN - 1364-548X

pISSN - 1359-7345

DOI - 10.1039/d0cc06356h

Subject(s) - chemiluminescence , thiol , chemistry , photochemistry , combinatorial chemistry , organic chemistry

We exploit the fluoride that is released via the para-fluoro-thiol reaction (PFTR) to cleave silyl ethers, turning the PFTR into an effective self-reporting chemiluminescence (CL) probe. The cleavage induces chemiluminescence and hence provides an optical read-out for the conversion of the PFTR. The PFTR chemiluminescence read-out is established on small molecule thiols, and subsequently expanded to polymers and networks.

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