Tetrel and pnictogen functionalised propargylidynes | Zendy

Richard A. Manzano | Zendy; Anthony F. Hill | Zendy; Rosemary Georgelin | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Open Access

Tetrel and pnictogen functionalised propargylidynes

Author(s) -

Richard A. Manzano,

Anthony F. Hill,

Rosemary Georgelin

Publication year - 2020

Publication title -

chemical communications

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.837

H-Index - 333

eISSN - 1364-548X

pISSN - 1359-7345

DOI - 10.1039/d0cc06196d

Subject(s) - pnictogen , chemistry , physics , superconductivity , condensed matter physics

The reaction of [W([triple bond, length as m-dash]CC[triple bond, length as m-dash]CSiMe 3 )(CO) 2 (Tp*)] (Tp* = tris(dimethylpyrazolyl)borate) with AgNO 3 affords {[W([triple bond, length as m-dash]CC[triple bond, length as m-dash]CAg)-(CO) 2 (Tp*)][AgNO 3 ]} n while [Hg{C[triple bond, length as m-dash]CC[triple bond, length as m-dash]W(CO) 2 (Tp*)} 2 ] with n BuLi affords [W([triple bond, length as m-dash]CC[triple bond, length as m-dash]CLi)(CO) 2 (Tp*)]. These anhydrous reagents allow the installation of main group elements (e.g., Si, Sn, Pb, P, As) as propargylidyne termini.

The content you want is available to Zendy users.

Already have an account? Click here to sign in.

Having issues? You can contact us here

Accelerating Research