Gleaned snapshots on the road to coordination polymers: heterometallic architectures based on Cu(i) metallaclips and 2,2′-bis-dipyrrin metalloligands | Zendy

Florent Moutier | Zendy; A. M. Khalil | Zendy; Stéphane A. Baudron | Zendy; Christophe Lescop | Zendy

Open Access

Gleaned snapshots on the road to coordination polymers: heterometallic architectures based on Cu(i) metallaclips and 2,2′-bis-dipyrrin metalloligands

Author(s) -

Florent Moutier,

A. M. Khalil,

Stéphane A. Baudron,

Christophe Lescop

Publication year - 2020

Publication title -

chemical communications

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.837

H-Index - 333

eISSN - 1364-548X

pISSN - 1359-7345

DOI - 10.1039/d0cc04862c

Subject(s) - metallacycle , chemistry , polymer , curse of dimensionality , polymer chemistry , nanotechnology , stereochemistry , materials science , physics , computer science , organic chemistry , optics , diffraction , machine learning , x ray crystallography

The assembly of binuclear Cu(i) metallaclips with 2,2'-bis-dipyrrin based metalloligands gives rise to a diversity of architectures featuring a recurring π-stacked compact tetranuclear metallacycle but differing in their nuclearity and dimensionality depending on the nature of the capping ligands and metal cations.

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