Thermo- and electro-switchable Cs⊂{Fe4–Fe4} cubic cage: spin-transition and electrochromism | Zendy

Jana Glatz | Zendy; LiseMarie Chamoreau | Zendy; Alexandrine Flambard | Zendy; JeanFrançois Meunier | Zendy; Azzedine Bousseksou | Zendy; Rodrigue Lescouëzec | Zendy

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Thermo- and electro-switchable Cs⊂{Fe₄–Fe₄} cubic cage: spin-transition and electrochromism

Author(s) -

Jana Glatz,

LiseMarie Chamoreau,

Alexandrine Flambard,

JeanFrançois Meunier,

Azzedine Bousseksou,

Rodrigue Lescouëzec

Publication year - 2020

Publication title -

chemical communications

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.837

H-Index - 333

eISSN - 1364-548X

pISSN - 1359-7345

DOI - 10.1039/d0cc04279j

Subject(s) - electrochromism , cage , spin (aerodynamics) , materials science , chemistry , crystallography , condensed matter physics , nanotechnology , physics , thermodynamics , electrode , mathematics , combinatorics

A mixed valence Cs⊂{Fe4-Fe4} cyanido-cube was synthesized and structurally characterized. The molecule, which is robust in solution, shows remarkable electronic versatility. Electrochromic properties associated with nine different electronic states are observed in solution together with a thermo-induced spin-transition in the solid state.

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