Hydride-encapsulated bimetallic clusters supported by 1,1-dithiolates | Zendy

YuJie Zhong | Zendy; JianHong Liao | Zendy; TzuHao Chiu | Zendy; YingYann Wu | Zendy; Samia Kahlal | Zendy; JeanYves Saillard | Zendy; C. W. Liu | Zendy

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Hydride-encapsulated bimetallic clusters supported by 1,1-dithiolates

Author(s) -

YuJie Zhong,

JianHong Liao,

TzuHao Chiu,

YingYann Wu,

Samia Kahlal,

JeanYves Saillard,

C. W. Liu

Publication year - 2020

Publication title -

chemical communications

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.837

H-Index - 333

eISSN - 1364-548X

pISSN - 1359-7345

DOI - 10.1039/d0cc03848b

Subject(s) - bimetallic strip , hydride , crystallography , chemistry , metal , organic chemistry

Two mixed-metal hydride clusters, corresponding to x = 3 and 4, were structurally characterized from a set of atomically precise heptanuclear clusters, Cu x Ag 7-x (H){S 2 P(O i Pr) 2 } 6 (x = 1-6). An interstitial hydride lying at the center of a tricapped tetrahedral cage was located and refined anisotropically by using X-ray data, and its presence acertained by multinuclear NMR spectroscopy and DFT calculations.

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