Open AccessUpper-rim functionalization and supramolecular polymerization of a feet-to-feet-connected biscavitand
Author(s) -
Daisuke Shimoyama,
Ryo Sekiya,
Takeharu Haino
Publication year - 2020
Publication title -
chemical communications
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.837
H-Index - 333
eISSN - 1364-548X
pISSN - 1359-7345
DOI - 10.1039/d0cc00933d
Subject(s) - surface modification , supramolecular chemistry , polymerization , polymer chemistry , materials science , chemistry , polymer science , nanotechnology , polymer , organic chemistry , molecule
An octaiodobiscavitand was synthesized via an aromatic Finkelstein iodination reaction in good yield. Sonogashira and Suzuki coupling reactions of the octaiodobiscavitand gave rise to upper-rim-functionalized biscavitands that self-assembled to form a supramolecular polymer in the solid state.
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