Second harmonic scattering from mass characterized 2D graphene oxide sheets
Author(s) -
Isabelle RussierAntoine,
Hussein Fakhouri,
Srestha Basu,
Franck Bertorelle,
Philippe Dugourd,
PierreFrançois Brevet,
Prajitha Velayudhan,
Sabu Thomas,
Nandakumar Kalarikkal,
Rodolphe Antoine
Publication year - 2020
Publication title -
chemical communications
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.837
H-Index - 333
eISSN - 1364-548X
pISSN - 1359-7345
DOI - 10.1039/d0cc00111b
Subject(s) - graphene , hyperpolarizability , materials science , scattering , oxide , femtosecond , molar mass , analytical chemistry (journal) , molecular physics , laser , optics , chemistry , nanotechnology , physics , polarizability , metallurgy , organic chemistry , chromatography , molecule , composite material , polymer
In this communication, we report the second harmonic scattering from mass characterized 2D graphene oxide sheets dispersed in an aqueous suspension, in the femtosecond regime at 800 nm laser excitation. Charge-detection mass-spectrometry, performing at the single sheet level, allows for an exhaustive molar mass distribution and thus concentration for these 2D nanomaterials samples. The orientation-averaged hyperpolarizability value is (1.36 ± 0.15) × 10 -25 esu as determined by the concentration-dependent harmonic scattering signal. In addition, the multi-photon excited fluorescence spectrum is characterized by a broad band in the visible range between 350 and 700 nm centered at about 500 nm.
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