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Unprecedented coupling reaction between two anionic species of a closo-decahydrodecaborate cluster and an Anderson-type polyoxometalate
Author(s) -
Manal Diab,
A.C. Mateo,
Joumada Al Cheikh,
Mohamed Haouas,
Alireza Ranjbari,
Flavien Bourdreux,
Daoud Naoufal,
Emmanuel Cadot,
Carles Bó,
Sébastien Floquet
Publication year - 2020
Publication title -
dalton transactions
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.98
H-Index - 184
eISSN - 1477-9234
pISSN - 1477-9226
DOI - 10.1039/c9dt04676c
Subject(s) - polyoxometalate , cluster (spacecraft) , electrochemistry , coupling (piping) , chemistry , computational chemistry , chemical physics , combinatorial chemistry , crystallography , materials science , organic chemistry , catalysis , computer science , electrode , metallurgy , programming language
A novel decahydrodecaborate-functionalized Anderson type polyoxometalate has been synthesized and characterized in solution by ESI-MS, various NMR techniques and electrochemical methods. DFT studies provide strong support to understand the properties of this hybrid system.

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