Synthesis of pyridyl carbyne complexes and their conversion to N-heterocyclic vinylidenes
Author(s) -
Benjamin J. Frogley,
Anthony F. Hill
Publication year - 2019
Publication title -
chemical communications
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.837
H-Index - 333
eISSN - 1364-548X
pISSN - 1359-7345
DOI - 10.1039/c9cc07760j
Subject(s) - carbyne , chemistry , combinatorial chemistry , organic chemistry , catalysis , carbene
A new synthetic approach to hetero-aryl substituted carbyne complexes has allowed the synthesis of pyridyl functionalised carbynes and bis(carbynes), alkylation of which affords the first N-heterocyclic vinylidene complexes.
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