Bis[diphenylphosphino]methane and its bridge-substituted analogues as chemically non-innocent ligands for H2 activation | Zendy

Nikolay V. Kireev | Zendy; Oleg A. Filippov | Zendy; Ekaterina S. Gulyaeva | Zendy; Elena S. Shubina | Zendy; Laure Vendier | Zendy; Yves Canac | Zendy; JeanBaptiste Sortais | Zendy; Noël Lugan | Zendy; Dmitry A. Valyaev | Zendy

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Bis[diphenylphosphino]methane and its bridge-substituted analogues as chemically non-innocent ligands for H₂ activation

Author(s) -

Nikolay V. Kireev,

Oleg A. Filippov,

Ekaterina S. Gulyaeva,

Elena S. Shubina,

Laure Vendier,

Yves Canac,

JeanBaptiste Sortais,

Noël Lugan,

Dmitry A. Valyaev

Publication year - 2020

Publication title -

chemical communications

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.837

H-Index - 333

eISSN - 1364-548X

pISSN - 1359-7345

DOI - 10.1039/c9cc07713h

Subject(s) - deprotonation , chemistry , hydride , medicinal chemistry , methane , bridge (graph theory) , stereochemistry , hydrogen , organic chemistry , medicine , ion

Deprotonation of fac-[(κ2P,P-Ph2PCH(R)PPh2)Mn(CO)3Br] (R = H, Me, Ph) produces the corresponding diphosphinomethanide derivatives fac-[(κ3P,C,P-Ph2PC(R)PPh2)Mn(CO)3], which are prone to activate H2 to form the hydride complexes fac-[(κ2P,P-Ph2PCH(R)PPh2)Mn(CO)3H]. The substitution of the dppm bridge improves dramatically the reaction efficiency and this was rationalized by DFT calculations.

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